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AWWA JAW18893

M00002989

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AWWA JAW18893 Journal AWWA - Using Isotope Dilution Mass Spectrometry to Determine Aqueous Trichloroacetic Acid

Journal Article by American Water Works Association, 04/01/1986

Norwood, Daniel L.;Christman, Russell F.;Johnson, J. Donald;Hass, J. Ronald

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The development, verification, and application of a method based on isotope dilution gas chromatography-mass spectrometry to determine aqueous trichloroacetic acid (TCAA) at the micrograms-per-liter level are described. The simultaneous determination of aqueous chloroform is also demonstrated. Trichloroacetic acid is shown to be a significant by-product of the chlorination of raw waters in the laboratory and to constitute a large fraction of the total organic halide (TOX) formed. Analysis of finished-water samples indicated that TCAA, like trihalomethanes, is ubiquitous. Positive correlations exist between the levels of TCAA in laboratory-chlorinated raw waters and in finished waters and measured TOX. Includes 20 references, tables, figures.