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AWWA ACE61732

M00000531

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AWWA ACE61732 Fast-Reacting Chlorinated Disinfection Byproduct Precursors

Conference Proceeding by American Water Works Association, 06/17/2005

Dickenson, Eric; Summers, R. Scott; Croue, Jean-Philippe; Gallard, Herve

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Relatively high trihalomethane (THM) and haloacetic acid (HAA) concentrations were formed from chlorination of six coagulatedtreated waters during the first couple of hours, where 35-45% of the 5 day TTHM formation and42-53% of the 5 day HAA5 formation were formed at 4 hours. For a given treated water thechlorine demand was not a good indicator of short- and long-term TTHM and DXAAformations, though the 5-day yields were consistently higher than the 1-day yields, where as theTXAAs formed per mg of chlorine consumed was the same for short- and long-term periods.Waters that were enhanced coagulated to a total organic carbon (TOC) value less than 4 mg/L and TSUVA value of 2L/mg-m and chlorinated for CT values less than 850 mg-min/L within 4 hours at a Cl2:TOC doseof 1.5 mg/mg, 20C, pH 8.0 and a Br-:TOC ratio less than 21 g/mg, formed TTHM and HAA5formations less than the MCLs. Includes 10 references, tables, figures.